Publications
Full List of Publications
2024
187. The coordination of alkali-metal nickelates to organic π-systems: Synthetic, structural and spectroscopic insights
A. M. Borys, L. Vedani, E Hevia
Dalton Trans. 2024, advance article
https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt00889h
186. Unlocking the Metalation Applications of TMP-powered Fe and Co(II) bis(amides): Synthesis, Structure and Mechanistic Insights
A. Logallo, L. C. H. Maddock, M. Mu, L. Gravogl, N. Jin, M. N. Peñas-Defrutos, K. Meyer,M. García-Melchor, E. Hevia
Angew. Chem. Int. Ed. 2024, early view
https://onlinelibrary.wiley.com/doi/10.1002/anie.202402907
185. Stoichiometric and Catalytic Lithium Nickelate-Mediated C–F Bond Alkynylation of Fluoroarenes
A. M. Borys, L. Vedani, E Hevia
J. Am. Chem. Soc. 2024, asap article
https://pubs.acs.org/doi/10.1021/jacs.4c02606
184. Enhancing the Metalating Power of ZnEt2 via Formation of an Alkyl/Alkoxide Potassium Zincate
J. Kocher, N. R. Judge, E. Hevia
Helv.Chim. Acta, 2024, 107, e202300237
https://doi.org/10.1002/hlca.202300237
183. Synthesis and Modular Reactivity of Low Valent Al/Zn Heterobimetallics Supported by Common Monodentate Amides
F. Dankert, E.Hevia
Chem. Eur. J. , 2024, 30, e202304336
https://doi.org/10.1002/chem.202304336
182. New Frontiers in Organosodium Chemistry as Sustainable Alternatives to Organolithium Reagents
D. A. Anderson, A. Tortajada, E. Hevia
Angew. Chem. Int. Ed. 2024, 63, e202313556
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202313556
2023
181. Main Group Metal Strategies for C–H and C–F Bond Activation and Functionalisation of Fluoroarenes
N.R. Judge, A. Logallo, E. Hevia
Chem. Sci. 2023, accepted artcle
https://pubs.rsc.org/en/content/articlelanding/2023/sc/d3sc03548d
180. Shedding Light on the Hidden Roles of Lithium in the Nickel-Catalyzed Cross-Coupling of Aryl Ethers
H. Liang, A. Borys, E. Hevia, M. E. Perrin, P. A. Payard
J. Am. Chem. Soc. 2023, 145, 19989
https://pubs.acs.org/doi/abs/10.1021/jacs.3c06647
179. Interaction and energy decomposition analyses to predict stability of tetraaryl square planar cobalt complexes
M. Mu, Al. Logallo, E. Hevia, M. Garcia-Melchor
ChemCatChem 2023, 15 e202300769
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202300769
178. Alkali-Metal Bases in Catalytic Hydrogen Isotope Exchange Processes
A. Tortajada, E. Hevia
Catal. Sci. Technol. 2023, 13, 4919
https://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00825H
177. Atom-efficient arylation of N-tosylimines mediated by cooperative ZnAr2/Zn(C6F5)2 combinations
A. M. Borys, T. Kunzmann, E. Hevia
Chem. Commun. 2023, 59, 7583.
https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc01490h
176. Sodium Mediated Deprotonative Borylation of Arenes Using Sterically Demanding B(CH2SiMe3)3: Unlocking Polybasic Behaviour and Competing Lateral Borane Sodiation
A. Tortajada, L. J. Bole, M. Mu, M. Stanford, M. N. Peñas-Defrutos, M. García-Melchor, E. Hevia
Chem. Sci. 2023, 14, 6538
https://pubs.rsc.org/en/content/articlelanding/2023/sc/d3sc01705b
175. Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
A. M. Borys, E. Hevia
Chem. Commun. 2023, 59, 7032
https://pubs.rsc.org/en/Content/ArticleLanding/2023/CC/D3CC01729J
174. Uncovering the Untapped Potential of the Use of Sodium Amides for Regioselective Arene Functionalisation
A. Tortajada, E. Hevia
Chimia, 2023, 77, 225
https://doi.org/10.2533/chimia.2023.225
173. New Frontiers in Alkali-Metal Nickelates
A. M. Borys, E. Hevia
Chimia, 2023, 77, 242
https://doi.org/10.2533/chimia.2023.242
172. Applying Na/Co(II) Bimetallic Partnerships to Promote Multiple Co–H Exchanges in Polyfluoroarenes
A. Logallo, E. Hevia
Chem. Commun., 2023, 59, 5383
171. Alkali-Metal-Alkoxide Powered Zincation of Fluoroarenes Employing Zinc Bis-Amide Zn(TMP)2
N. Judge, E. Hevia
Angew. Chem. Int. Ed. 2023, 62, e202303099
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202303099
170. Structural and synthetic insights on oxidative homocouplings of alkynes mediated by alkali-metal manganates
P. Mastropierro, A. W. J. Platten, A. R. Kennedy, E. Hevia, M. Uzelac
Chem. Eur. J, 2023, 29, e202300593
https://doi.org/10.1002/chem.202300593
169. Structural and synthetic insights into the chemistry of lithium tetraorganozincates
A. M. Borys, M. Dell’Aera, V. Capriati, E. Hevia
Adv. Organomet. Chem 2023, 80, 1
https://doi.org/10.1016/bs.adomc.2022.11.001
168. Highly Reactive Hydrocarbon Soluble Alkylsodium Reagents for Benzylic Aroylation of Toluenes using Weinreb Amides
D. E. Anderson, A. Tortajada, E. Hevia
Angew. Chem. Int. Ed. 2023, 62, e202218498
https://doi.org/10.1002/anie.202218498
167. Diphenylacetylene Stabilised Alkali-Metal Nickelates: Synthesis, Structure and Catalytic Applications
A. M. Borys, E. Hevia,
Dalton Trans. 2023, 52, 2098
https://doi.org/10.1039/D3DT00069A
2022
166. Continuous, stable, and safe organometallic reactions in flow at room temperature assisted by deep eutectic solvents
F. F. Mulks, B. Pinho, A. W.J. Platten, M. R. Andabili, A. J. Expósito, K. J. Edler, E. Hevia, L. Torrente-Murciano
Chem 2022, 8, 3382.
https://doi.org/10.1016/j.chempr.2022.11.004
165. Building Square Planar Cobalt (II) Complexes via Sodium Mediated Cobaltation of Fluoroarenes
A. Logallo, M. Mu, M. García-Melchor, E. Hevia
Angew. Chem. Int. Ed. 2022, 134, e202213246
https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202213246
164. Perdeuteration of Arenes via Hydrogen Isotope Exchange Catalyzed by the Superbasic Sodium Amide Donor Species NaTMP·PMDETA
A. Tortajada, E. Hevia
J. Am. Chem. Soc., 2022, 144, 20237
https://pubs.acs.org/doi/abs/10.1021/jacs.2c09778
163. Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX·LiX (X = Cl, Br)
A. Kremsmair, A. S. Sunagatullina, L. J. Bole, P. Mastropierro, S. Graßl, H. R. Wilke, E. Godineau, E. Hevia, P. Knochel
Angew. Chem. Int. Ed. 2022, 61, e202210491
https://onlinelibrary.wiley.com/doi/10.1002/anie.202210491
162. Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent-Induced Dissociation Effects
G. M. Ballmann, T. X. Gentner, A. R. Kennedy, E. Hevia, R. E. Mulvey
Chem. Eur. J. 2022, early view, e202201716
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.202201716
161. Towards Hexagonal Planar Nickel: A Dispersion-Stabilised Tri-Lithium Nickelate
A, M. Borys, L. A. Malaspina, S. Grabowsky, E. Hevia
Angew. Chem. Int. Ed. 2022, 61, e202209797
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202209797
160. Gram-Scale Synthesis, Isolation and Characterisation of Sodium Organometallics: nBuNa and NaTMP
A. Tortajada, D. E. Anderson, E. Hevia
Helv. Chim. Acta, 2022, 105, e202200060
https://onlinelibrary.wiley.com/doi/10.1002/hlca.202200060
159. Enhancing Metalating Efficiency of the Sodium Amide NaTMP in Arene Borylation Applications
L. J. Bole, A. Tortajada, E. Hevia
Angew. Chem. Int. Ed. 2022, 61, e202204262
https://doi.org/10.1002/anie.202204262
158. Alkali Metal Metal(ates) Containing Divalent Earth Abundant Transition Metals
A. Logallo, E. Hevia
Chimia, 2022, 76, 336.
https://doi.org/10.2533/chimia.2022.336
157. Unmasking the constitution and bonding of the proposed lithium nickelate “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand
R. J. Somerville, A. M. Borys, M. Perez-Jimenez, A. Nova, D. Balcells, L. A. Malaspina, S. Grabowsky, E. Carmona, E. Hevia, J. Campos
Chem. Sci. 2022, 13, 5268-5276
https://doi.org/10.1039/D2SC01244H
156. Mechanisms of the Nickel-Catalysed Hydrogenolysis and Cross-Coupling of Aryl Ethers
A. M. Borys, E. Hevia
Synthesis, 2022, 2976-2990
https://www.thieme-connect.com/products/ejournals/abstract/10.1055/a-1806-4513
155. Metallation of Sensitive Fluoroarenes using a Potassium TMP-Zincate Supported by a Silyl(bis)amido Ligand
P. Mastropierro, A. R. Kennedy, E. Hevia
Chem Commun. 2022, 58, 5292
https://doi.org/10.1039/D2CC00979J
154. Activation of polar organometallic reagents with alkali–metal alkoxides
L. J. Bole, E. Hevia
Nature Synthesis, 2022, 1, 195
https://doi.org/10.1038/s44160-022-00040-5
153. Hydrophosphinylation of Styrenes Catalysed by Well-Defined s-Block Bimetallics
A. W. J. Platten, A. M. Borys, E. Hevia
ChemCatChem 2022, 14, e202101853
https://doi.org/10.1002/cctc.202101853
152. Assessing Alkali-Metal Effects in the Structures and Reactivity of Mixed-Ligand Alkyl/Alkoxide Alkali-Metal Magnesiates
N. R. Judge, L. J. Bole, E. Hevia
Chem. Eur. J. 2022, 28, e2021041
https://doi.org/10.1002/chem.202104164
2021
151. Structural and Synthetic Insights into Sodium-Mediated-Ferration of Fluoroarenes
L. C. H. Maddock, A. R. Kennedy, E. Hevia
Helv. Chim. Acta, 2021, 104, e202100206
https://onlinelibrary.wiley.com/doi/10.1002/hlca.202100206
150. Regioselective Synthesis of 1,5-Disubstituted 1,2,3-Triazoles Catalyzed by Cooperative s-Block Bimetallics
M. De Tullio, A. M. Borys, A. Hernán-Gómez, A. R. Kennedy, E. Hevia
Chem Catalysis, 2021, 1, 1308
https://doi.org/10.1016/j.checat.2021.09.016
149. The Anionic Pathway in Nickel-Catalysed Cross-Coupling of Aryl Ethers
A. M. Borys, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 24659.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202110785
148. Atom-efficient transition-metal-free arylation of N,O-acetals using diarylzinc reagents through Zn/Zn cooperativity
A. M. Borys, J. M. Gil-Negrete, E. Hevia
Chem. Commun. 2021, 57, 8905.
https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc04137a
147. Exploiting chemical cooperativity in main-group bimetallic catalysis
A. M. Borys, E. Hevia
Trends Chem. 2021, 3, 803.
https://doi.org/10.1016/j.trechm.2021.07.006
146. Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilide Ligands
L. C. H. Maddock, R. Morton, A. R. Kennedy, E. Hevia
Chem. Eur. J. 2021, 27, 15181.
https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.202102328
145. Advancing Air- and Moisture-Compatible s-Block Organometallic Chemistry Using Sustainable Solvents
S. E. García-Garrido, A. Presa Soto, E. Hevia, J.García-Álvarez
Eur. J. Inorg. Chem. 2021, 3116.
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100347
Cover Picture: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100601
144. Progressing the Frustrated Lewis Pair Abilities of N-Heterocyclic Carbene/GaR3 Combinations for Catalytic Hydroboration of Aldehydes and Ketones
L. J. Bole, M. Uzelac, A. Hernán-Gómez, A. R. Kennedy, C. T. O’Hara, E.Hevia
Inorg. Chem. 2021, asap article
https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.1c01276
143. Facilitating the Ferration of Aromatic Substrates through Intramolecular Sodium Mediation
L. C. H. Maddock, M. Mu, A. R. Kennedy, M. Garcia-Melchor, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 15296
https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202104275
142. Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS)2] Catalysed Transfer Hydrogenation
T. X. Gentner, E. Hevia, R. E. Mulvey
ChemCatChem. 2021, 13, 2371.
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202100218
141. Untangling the Complexity of Mixed Lithium/Magnesium Alkyl/Alkoxy Combinations Utilised in Br/Mg Exchange Reactions
L. J. Bole, N. R. Judge, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 7626
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202016422
140. Exploiting deprotonative co-complexation to access potassium metal(ates) supported by a bulky silyl(bis)amide ligand
P. Mastropierro, A. R. Kennedy, E. Hevia
Eur. J. Inorg. Chem. 2021, 1016
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202001051
Front Cover: https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202100133
139. Beyond Ni{N(SiMe3)2}2: Synthesis of a Stable Solvated Sodium Tris- Amido Nickelate
A. M. Borys, E. Hevia
Organometallics, 2021, 40, 442
https://pubs.acs.org/doi/abs/10.1021/acs.organomet.0c00785
138. Tandem Mn-I exchange and homocoupling processes mediated by a synergistically operative lithium manganate
M. Uzelac, P. Mastropierro, M. de Tullio, I. Borilovic, M. Tarres, A. R. Kennedy, G. Aromí, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 3247
https://onlinelibrary.wiley.com/doi/10.1002/anie.202013153
137. Main Group Bimetallic Partnerships for Cooperative Catalysis
J. M. Gil-Negrete, E. Hevia
Chem. Sci. 2021, 12, 1982 DOI;10.1039/d0sc05116k
https://doi.org/10.1039/D0SC05116K
136. Regioselective Bromine/Magnesium‐Exchange for Selective Functionalization of Polyhalogenated Aromatics and Heterocycles
A. Desaintjean, T. Haupt, L. J. Bole, N. R. Judge, E. Hevia, P. Knochel
Angew. Chem. Int. Ed. 2021, 60, 1513
https://doi.org/10.1002/anie.202012496
2020
135. Lithium-mediated Ferration of Fluoroarenes
L.C. H. Maddock. A. R. Kennedy, E. Hevia
CHIMIA, 2020, 74, 866.
https://doi.org/10.2533/chimia.2020.866
134. Towards a Paradigm Shift in Polar Organometallic Chemistry
E. Hevia
CHIMIA, 2020, 74, 681.
https://doi.org/10.2533/chimia.2020.681
133. Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali-Metal Amides under Air
F. F. Mulks, L. J. Bole, L. Davin, A. Hernán-Gómez, A. R. Kennedy, J. García-Álvarez, E. Hevia
Angew. Chem. Int. Ed. 2020, 59, 19021
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202008512
132. Combination of Organocatalytic Oxidation of Alcohols and Highly-Polar Organometallic Chemistry (RLi) in Aqueous Media, at Room Temperature and Under Aerobic Conditions
D. Elorriaga, M. J. Rodríguez-Álvarez, N. Ríos-Lombardía, F. Morís, A. Presa Soto, J. González-Sabín, E. Hevia, J. García-Álvarez
Chem. Commun., 2020, 56, 8932
https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc03768k#!divAbstract
131. Structurally Mapping Alkyl and Amide Basicity in Zincate Chemistry: Di-versity in the Synthesis of Mixed Sodium-Zinc Complexes and their Ap-plications in Enolate Formation
P. Mastropierro, Z. Livingstone,.S. D. Robertson,. A. R. Kennedy, E. Hevia
Organometallics, 2020, 39, 23, 4273 doi: 10.1021/acs.organomet.0c00339
https://pubs.acs.org/doi/abs/10.1021/acs.organomet.0c00339
130. Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents
M. Fairley, L. J. Bole, F. F. Mulks, L. Main, A. R. Kennedy, C. T. O’Hara, J. Garcia-Alvarez, E. Hevia.
Chem. Sci., 2020, 11, 6500
https://pubs.rsc.org/en/content/articlehtml/2020/sc/d0sc01349h
129. A regioselectively 1,1’,3,3’-tetrazincated ferrocene complex displaying core and peripheral reactivity
G. W. Honeyman, D. R. Armstrong, W. Clegg, E. Hevia, A. R. Kennedy, D. L. Ramsay, R. E. Mulvey, J. A. Parkinson, S. A. Orr, R. McLellan, S. D. Robertson, S. Towie.
Chem. Sci. 2020, 11, 6510
https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc01612h#!divAbstract
128. Boosting Conjugate Addition to Nitroolefins Using Lithium Tetraorganozincates: Synthetic Strategies and Structural Insights.
M. Dell’Aera, F. M. Perna, P. Vitale, A. Altomare, A. Palmieri, L. C. H. Maddock, L. J. Bole, A. R. Kennedy, E. Hevia, V. Capriati.
Chem. Eur. J. 2020, 26, 8742
https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.202001294
2019
127. Preparation of Polyfunctional Arylzinc Organometallics in Toluene by Halogen/Zinc Exchange Reactions
M. Balkenhohl, D. S. Ziegler, A. Desaintjean, L. J. Bole, A. R. Kennedy, E. Hevia P. Knochel.
Angew. Chem. Int. Ed., 2019, 58, 12898. (VIP article).
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201906898
126. s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols
M. Fairley, L. Davin, A. Hernan-Gomez, J. Garcia-Alvarez, C. T. O’Hara, E. Hevia.
Chem. Sci. 2019, 10, 5821.
https://pubs.rsc.org/en/content/articlehtml/2019/sc/c9sc01598a
125. Molybdenum and rhenium carbonyl complexes containing thiolato ligands
P. Cañadas, S. Ziegler, S. Fombona, E. Hevia, D. Miguel, J. Pérez, L. Riera.
J. Organomet. Chem. 2019, 896, 113. (Invited contribution to special edition in memoriam to Prof. Pascual Royo)
https://www.sciencedirect.com/science/article/pii/S0022328X19302359
124. Organolithium Initiated Polymerization of Olefins in Deep Eutectic Solvents under Aerobic Conditions. Sustainable Route to Homopolymers, Random Copolymers and Block Copolymers
A. Sánchez-Condado, G. A. Carriedo, A. Presa Soto, M. J. Rodríguez-Álvarez, J. García-Álvarez, E. Hevia
ChemSusChem, 2019, 12, 3134.
https://onlinelibrary.wiley.com/doi/full/10.1002/cssc.201900533
123. Alkali-Metal and Stoichiometric Effects in Intermolecular Hydroamination Catalysed by Lithium, Sodium and Potassium Magnesiates
L. Davin, A. Hernán-Gómez, C. McLaughlin A.R. Kennedy, R. McLellan, E. Hevia
Dalton Trans, 2019, 48, 8122.
https://pubs.rsc.org/en/content/articlelanding/2019/dt/c9dt00923j/unauth#!divAbstract
122. Magnesium-Mediated Arylation of Amines via C-F Bond Activation of Fluoroarenes
L. J. Bole, L. Davin, A.R. Kennedy, R. McLellan, E. Hevia
Chem. Commun., 2019, 55, 4339.
https://pubs.rsc.org/en/content/articlelanding/2019/cc/c9cc01670h#!divAbstract
121. Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH2SiMe3)3 Metallation Reactions
R. McLellan, M. Uzelac, L. J. Bole, J. M. Gil-Negrete, D. R. Armstrong, Alan R. Kennedy, R. E. Mulvey, E. Hevia
Synthesis, 2019, 51, 1207 (Feature Article, Invited contribution to Golden Anniversary Issue)
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0037-1611646
2018
120. The future of Polar Organometallic Chemistry Written in Bio-Based Solvents and Water
J. Garcia-Alvarez, E. Hevia, V. Capriati
Chem. Eur. J. 2018, 24, 14854 (Concept Article).
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201802873
119. Exploiting Synergistic Effects in Organozinc Chemistry for Direct Stereoselective C-Glycosylation Reactions at Room Temperature
A. Hernán-Gómez, S. A. Orr, M. Uzelac, A. R. Kennedy, S. Barroso, X. Jusseau, S. Lemaine, V. Farina, E. Hevia
Angew. Chem. Int. Ed, 2018
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201805758
118. Structural and Synthetic Insights into Pyridine Homocouplings Mediated by a β-Diketiminato Magnesium Amide Complex
L. A. Davin, W. Clegg, A. R. Kennedy, M. R. Probert, R. McLellan, E. Hevia.
Chem. Eur. J. 2018, 24, 14830
https://onlinelibrary.wiley.com/doi/10.1002/chem.201803297
117. Molecular Manipulations of a Utility Nitrogen Heterocyclic Carbene by Sodium Magnesiate Complexes and Transmetallation complexes with Gold Complexes
A. Hernán-Gómez, M. Uzelac, S. E. Baillie, D. R. Armstrong, A. R. Kennedy. M. A. Fuentes, E. Hevia
Chem. Eur. J. 2018
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201802008
116. Donor-influenced structure-activity correlations in stoichiometric and catalytic reactions of lithium monoamido-monohydrido-dialkylaluminates
R. E. Mulvey, J. Okuda, L. E. Lemmerz, R. McLellan, N. R. Judge, A. R. Kennedy, S. Orr, M. Uzelac, E. Hevia, S. D.Robertson
Chem. Eur. J. 2018
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201801541
115. Polar organometallic strategies for regioselective C–H metallation of N-heterocyclic carbenes
M. Uzelac, E. Hevia
Chem. Commun. 2018, 54, 2455
https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc00049b#!divAbstract
114. Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications
V. A. Pollard, S. A. Orr, R. McLellan, A. R. Kennedy, E. Hevia, R. E. Mulvey
Chem. Commun. 2018, 54, 1233
https://pubs.rsc.org/en/content/articlelanding/2018/cc/c7cc08214b#!divAbstract
113. Introducing Glycerol as a Sustainable Solvent to Organolithium Chemistry: Ultrafast Chemoselective Addition of Aryllithium Reagents to Nitriles under Air and at Ambient Temperature
M. J. Rodriguez-Alvarez, J. Garcia-Alvarez, M. Uzelac, M. Fairley, C. T. O’Hara, E. Hevia
Chem. Eur. J. 2018, 24, 1720
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201705577
112. Utilising Sodium‐Mediated Ferration for Regioselective Functionalisation of Fluoroarenes via C−H and C−F Bond Activations
L. C. H. Maddock, T. Nixon, A. R. Kennedy, M. R. Probet, W. Clegg, E. Hevia
Angew. Chem. Int. Ed. 2018, 57, 187
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201709750
2017
111. Ligand-induced reactivity of -diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C–H or C–F bond activations
L. Davin, R. McLellan, A. R. Kennedy, E. Hevia
Chem. Commun., 2017, 53, 11650
https://pubs.rsc.org/en/content/articlelanding/2017/CC/C7CC07193K#!divAbstract
110. LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps
R. McLellan, M. Uzelac, A. R. Kennedy, E. Hevia, R. E Mulvey
Angew. Chem. Int. Ed, 2017, 56, 9566
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201706064
109. Trans-metal-trapping meets Frustated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3 Induced C-H Functionalizations
M. Uzelac, A. R. Kennedy, E. Hevia
Ignor. Chem. 2017, 56, 8615
https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b00549
108. C-N bond activation and ring opening of a saturated N heterocyclic carbene via lateral alkali-metal-mediated metallation (AMMM)
A. Hernán-Gómez, A. R. Kennedy, E. Hevia
Angew. Chem. Int. Ed, 2017, 56, 6632
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201702246
107. Synthetic, Structural and Magnetic Implications of Introducing 2,2’Dipyridylamide to Sodium-Ferrate Complexes
L.C.H. Maddock, I. Borliovic, J. McIntyre, A.R. Kennedy, G. Aromí, E. Hevia
Dalton Trans. 2017, 46, 6683
https://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt01319a#!divAbstract
106. Regioselective Magnesiation of N-Heterocyclic molecules: securing insecure cyclic anions by a β-diketiminate-magnesium clamp
L. Davin, R. McLellan, A. Hernán-Gómez, A. R. Kennedy, M. Mertens, I. Stepek, E. Hevia
Chem. Commun., 2017, 53, 3653
https://pubs.rsc.org/-/content/articlelanding/2017/cc/c6cc09675a#!divAbstract
105. Exploiting Deep Eutectic Solvents and Organolithium Reagen Partnerships Chemiselective Ultrafast Addition to Imines and Quinolines Under Aerobic Ambient Temperature Conditions
C. Vidal, J. Garcia-Alvarez, A. Hernán-Gómez, A. R. Kennedy, E. Hevia
Angew. Chem. Int. Ed. 2016, 55, 16145
(Highlighted in Chemistry World)
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201609929
104. Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines
M. De Tullio, A. Hernán-Gómez, Z. Livingstone, W. Clegg, A. R. Kennedy, R. W. Harrington, A. Antiñolo, A. Martínez, F. Carrillo-Hermosilla, E. Hevia
Chem. Eur. J. 2016, 22, 17646
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201602906
103. Heavier alkali-metal gallates as platforms for accessing functionalized abnormal NHC carbene-gallium complexes
M. Uzelac, A. R. Kennedy, A. Hernán-Gómez, M. A. Fuentes, E. Hevia
Z. Anorg. Allg. Chem., 2016, 642, 1241 (Invited contribution to special issue on N-Heterocyclic Carbenes)
https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.201600310
102. Understanding the subtleties of frustrated Lewis pair activation of carbonyl compounds by N-Heterocyclic carbene/alkyl gallium pairings
M. Uzelac, D. R. Armstrong, A. R. Kennedy, E. Hevia
Chem. Eur. J. 2016, 22, 15826
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201603597
101. Synthesis, structure and solution studies on mixed aryl/alkyl lithium zincates
A. J. Roberts, A. R. Kennedy, R. McLellan, S. D. Robertson, E. Hevia
Eur. J. Inorg. Chem., 2016: 4752
https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201601020
100. Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping
M. Uzelac, A. R. Kennedy, E. Hevia, R. E. Mulvey
Angew. Chem. Int. Ed.2016, 55, 13147
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201607284
99. Structural and Magnetic Diversity in Alkali-Metal Manganate Chemistry: Evaluating Donor and Alkali-Metal Effects in Co-complexation Processes
M. Uzelac, I. Borilovic, M. Amores, T. Cadenbach, A. R. Kennedy, G. Aromí, and E. Hevia
Chem. Eur. J. 2016, 22, 4843 (VIP Paper)
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201504956
98. Assessing the reactivity of sodium alkyl-magnesiates towards quinoxaline:single elctron transfer (SET) vs. nucleophilic alkylation processes
Z.Livingstone, A. Hernán-Gómez, S. E. Baillie, D. R. Armstrong, L. M. Carrella, W. Clegg, R. W. Harrington, A. R. Kennedy, E. Rentschler and E. Hevia
Dalton Trans., 2016, 45, 6175
https://pubs.rsc.org/en/content/articlelanding/2016/dt/c5dt04044b#!divAbstract
2015
97. Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule
A. Martínez-Martínez, M. A. Fuentes, A. Hernán-Gómez, E. Hevia, A. R. Kennedy, R. E. Mulvey, C.T.O'Hara
Angew. Chem. Int. Ed. 2015, 54, 14075
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201509531
96. Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities
J. Garcia-Alvarez, E. Hevia, V. Capriati
Eur. J. Org. Chem. 2015, 6779.
https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201590088
95. Accessing Sodium Ferrate Complexes Containing Neutral and Anionic N-Heterocyclic Carbene Ligands: Structural, Synthetic, and Magnetic Insights
L. C. H. Maddock, T. Cadenbach, A. R. Kennedy, I. Borilovic, G. Aromí, E. Hevia
Inorg. Chem. 2015, 54, 9201.
https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.5b01638
94. Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights
M. Uzelac, A. Hernán-Gómez, D. R. Armstrong, A. R. Kennedy, E. Hevia
Chem. Sci. 2015, 6, 5719.
https://pubs.rsc.org/en/content/articlelanding/2015/sc/c5sc02086g#!divAbstract
93. Zincate-Mediated Arylation Reactions of Acridine: Pre- and Postarylation Structural Insights
A. Hernan-Gomez, E. Herd, M. Uzelac, T. Cadenbach, A. R. Kennedy, I. Borilovic, G. Aromi, E. Hevia
Organometallics, 2015, 34, 2614.
https://pubs.acs.org/doi/abs/10.1021/om501251q
92. Structurally Defined Zincated and Aluminated Complexes of Ferrocene Made by Alkali-Metal Synergistic Syntheses
W. Clegg, E. Crosbie, S. H. Dale-Black, E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey, D. L. Ramsay, S. D. Robertson
Organometallics, 2015, 34, 2580.
https://pubs.acs.org/doi/abs/10.1021/om5012352
91. Two alternative approaches to access mixed hydride-amido zinc complexes: synthetic, structural and solution implications
A. J. Roberts, W. Clegg, A. R. Kennedy, M. Probert, S. D. Robertson, E. Hevia
Dalton Trans. 2015, 44, 8169.
https://pubs.rsc.org/en/content/articlelanding/2015/dt/c5dt00312a#!divAbstract
2014
90. Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air
C. Vidal, J. Garcia-Alvarez, A. Hernan-Gomez, A. R. Kennedy, E. Hevia
Angew. Chem. Int. Ed. 2014, 53, 5969.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201400889
89. Potassium-alkyl magnesiates: synthesis, structures and Mg-H exchange applications of aromatic and heterocyclic substrates
S. E. Baillie, T. Bluemke, W. Clegg, A. R. Kenedy, J. Klett, L. Russo, M. de Tullio, E. Hevia,
Chem. Commun. 2014, 50, 12859.
https://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc05305b#!divAbstract
88. New supramolecular assemblies in heterobimetallic chemistry: synthesis of a homologous series of unsolvated alkali-metal zincates
D. R. Armstrong, H. S. Emerson, A. Hernan-Gomez, A. R. Kennedy, E. Hevia
Dalton Trans. 2014, 43, 14229.
https://pubs.rsc.org/en/content/articlelanding/2014/dt/c4dt01131g/unauth#!divAbstract
87. Structural and reactivity insights in Mg Zn hybrid chemistry: Zn-I exchange and Pd-catalysed cross-coupling applications of aromatic substrates
T. D. Bluemke, W. Clegg, P. Garcia-Alvarez, K. Koszinowski, M. D. Call, L. Russo, E. Hevia,
Chem. Sci. 2014, 5, 3552.
https://pubs.rsc.org/en/content/articlelanding/2014/sc/c4sc01263a/unauth#!divAbstract
86. TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation alkylaluminium-trapping reagents?
D. R. Armstrong, E. Crosbie, E. Hevia, R. E. Mulvey, D. L. Ramsay, S. D. Robertson
Chem. Sci. 2014, 5, 3031.
https://pubs.rsc.org/en/content/articlelanding/2014/sc/c4sc01108b#!divAbstract
85. Organozinc Pivalate Reagents: Segregation, Solubility, Stabilization, and Structural Insights
A. Hernan-Gomez, E. Herd, E. Hevia, A. R. Kennedy, P. Knochel, K. Koszinowski, S.M. Manolikakes, R. E. Mulvey, C. Schnegelsberg
Angew. Chem. Int. Ed. 2014, 53, 2706.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201309841#support-information-section
84. Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulkybis(amido) ligand: deprotomagnesiation reactions of nitrogen-based aromatic substrates
D. R. Armstrong, W. Clegg, A. Hernan-Gomez, A. R. Kennedy, Z. Livingstone, S. D. Robertson, L. Russo, E. Hevia
Dalton Trans, 2014, 43, 4361 (Invited contribution to themed issue New Talent: Europe)
https://pubs.rsc.org/en/Content/ArticleLanding/DT/2014/C3DT52639A#!divAbstract
2013
83. Donor-Activated Lithiation and Sodiation of Trifluoromethylbenzene: Structural, Spectroscopic, and Theoretical Insights
J. A. Garden, D. R. Armstrong, W. Clegg, J. Garcia-Alvarez, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. D. Robertson, L. Russo
Organometallics, 2013, 32, 5481.
https://pubs.acs.org/doi/abs/10.1021/om4007664
82. Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene(NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(I) complex with a NHC anion
D. R. Armstrong, S. E. Baillie, V. L. Blair, N. G. Chabloz, J. Diez, J. Garcia-Alvarez, A. R. Kennedy, S. D. Robertson, E. Hevia
Chem. Sci. 2013, 4, 4259.
https://pubs.rsc.org/en/content/articlelanding/2013/sc/c3sc52101j#!divAbstract
81. Concealed Cyclotrimeric Polymorph of Lithium 2,2,6,6-Tetramethylpiperidide Unconcealed: X-Ray Crystallographic and NMR Spectroscopic Studies
E. Hevia, A. R. Kennedy, R. E. Mulvey, D. L. Ramsay, S. D. Robertson
Chem. Eur. J. 2013, 19, 14069.
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201302709
80. Developing Catalytic Applications of Cooperative Bimetallics: Competitive Hydroamination Trimerization Reactions of Isocyanates Catalysed by Sodium Magnesiates
A. Hernán-Gómez, T. D. Bradley, A. R. Kennedy, Z. Livingstone, S. D. Robertson, E. Hevia,
Chem. Commun. 2013, 49, 8659.
https://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc45167d#!divAbstract
79. Isomeric and chemical consequences of the direct magnesiation of 1,3-benzoazoles using diketiminate-stabilized magnesium bases
S. E. Baillie, V. L. Blair, T. Bradley, W. Clegg, J. Cowan, R. Harrington, A.Hernan-Gomez, A. R. Kennedy, Z. Livingstone, E. Hevia
Chem. Sci. 2013, 4, 1895.
https://pubs.rsc.org/en/content/articlelanding/2013/sc/c3sc22326d/unauth#!divAbstract
78. Co-complexation Syntheses, Structural Characterization, and DFT studies of a novel series of Polymeric Alkali-Metal Tetraorganogallates
D. R. Armstrong, E. Brammer, T. Cadenbach, E. Hevia, A. R. Kennedy
Organometallics, 2013, 32, 480.
https://pubs.acs.org/doi/abs/10.1021/om3009469
2012
77. Synthesis, structural elucidation, and diffusion-ordered NMR studies of homoleptic alkyllithium magnesiates: donor-controlled structural variations in mixed-metal chemistry
S. D. Baillie, W. Clegg, P. Garcia-Alvarez, E. Hevia, A. R. Kennedy, J. Klett, L. Russo
Organometallics, 2012, 31, 5131-5142.
http://pubs.acs.org/doi/abs/10.1021/om300477m
76. Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire
T. Cadenbach, E. Hevia, A. R. Kenendy, R. E. Mulvey, J. A. Pickrell, S. D. Robertson
Dalton Transactions, 2012, 41,10141-10144.
https://pubs.rsc.org/en/content/articlelanding/2012/dt/c2dt31061a#!divAbstract
75. New Lithium-Zincate Approaches for the Selective Functionalisation of Pyrazine: Direct Dideprotozincation vs Nucleophilic Alkylation
S. E. Baillie, V. L. Blair, D. C. Blakemore, D. Hay, E. Hevia, A. R. Kenendy, D. C. Pryde
Chem. Commun. 2012, 48, 1985-1987.
https://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc16959b#!divAbstract
74. Assessing the reactivity of sodium zincate [(TMEDA)Na(TMP)ZntBu2] towards benzoylferrocene: deprotonative metalation vs alkylation reactions
E. Hevia, A. R. Kennedy, M. D. McCall
Dalton Trans 2012, 41, 98-103
https://pubs.rsc.org/en/content/articlelanding/2012/dt/c1dt11465d#!divAbstract
2011
73. Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated-zincation with indirect sodiation-dialkylzinc co-complexation
D. R. Armstrong, L. Balloch, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, S. D. Robertson
Belstein J. Org. Chem. 2011, 7, 1234-1248.
https://www.beilstein-journals.org/bjoc/articles/7/144
72. Magnesium-Mediated Benzothiazole Activation: a Room Temperature Cascade of C-H Deprotonation, C-C Coupling, Ring-Opening and Nucleophilic Addition Reactions
V. L. Blair, W. Clegg, A. R. Kennedy, Z. Livingstone, L. Russo, E. Hevia
Angew. Chem. Int. Ed. 2011, 50, 9857-9860.
https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.201103275
71. A record-breaking Magnesium-Hydride Molecular Cluster: Implications for hydrogen storage
E. Hevia, R. E.Mulvey
Angew. Chem. Int. Ed. 2011, 50, 9242-9243.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201102978
70. Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes
E. Hevia, R. E. Mulvey
Angew. Chem. Int. Ed. 2011, 50, 6448-6450.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201102054
69. Alkali-metal mediated zincation of N-heterocyclic substrates using the lithium zincate complex, (THF)Li(TMP)Zn(tBu)2 and applications in in situ cross-coupling reactions
V. L. Blair, D. C. Blakemore, D. Hay, E. Hevia, D. C. Pryde
Tet. Lett. 2011, 52, 4590-4594.
https://www.sciencedirect.com/science/article/pii/S0040403911010495
68. A New Polymeric alkyl/alkoxide magnesium-sodium inverse crown complex
S. E. Baillie, V. L. Blair, E. Hevia, A. R. Kennedy
Act Cryst., 2011, C67, m249-m251.
http://scripts.iucr.org/cgi-bin/paper?em3041
67. Expanding Mg-Zn hybrid chemistry: Inorganic salt effects in addition reactions of organozinc reagents to trifluoromethyl acetophenone and implications for a synergistic lithium-magnesium-zinc activation
D. R. Armstrong, W. Clegg, P. García-Alvarez, M. D. McCall, A. R. Kennedy, L. Russo, E. Hevia
Chem. Eur. J, 2011 17, 8333-8341.
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201100866
66. Shedding New Light on ZnCl2-Mediated Addition Reactions of Grignard Reagents to Ketones: Structural Authentication of Key Intermediates and Diffusion-Ordered NMR Studies
D. R. Armstrong, W. Clegg, P. García-Alvarez, E. Hevia, M. D. McCall, L. Nuttall, A. R. Kennedy, L. Russo
Chem. Eur. J, 2011, 17, 4470.
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201002544
65. Synthesis and Characterization of an Infinite Sheet of Metal-Alkyl Bonds: Unfolding the Elusive Structure of an Unsolvated Alkali-Metal Trisalkylmagnesiate
S. E. Baillie, W. Clegg, P. Garcia-Alvarez, E. Hevia, A. R. Kennedy, J. Klett, L. Russo
Chem. Commun, 2011, 47, 388-390.
https://pubs.rsc.org/EN/content/articlelanding/2011/cc/c0cc02164d#!divAbstract
2010
64. Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates
D. R. Armstrong,.V. L. Blair, W. Clegg, S. H. Dale, J. García-Alvarez, E. Hevia, G. W. Honeyman, R. E. Mulvey, L. Russo
J. Am. Chem. Soc. 2010, 132, 9480-9487.
https://pubs.acs.org/doi/abs/10.1021/ja1038598
63. Exposing the Hidden Complexity of Stoichiometric and Catalytic Metathesis Reactions byElucidation of Mg-Zn Hybrids
J. Z. Chua, P. García-Álvarez, E. Hevia, A. R. Kennedy, M. D. McCall
Proc. Natl. Acad. Sci. USA, 2010, 107, 5294-5299.
https://www.pnas.org/content/107/12/5294.abstract
62. New Insights into Addition Reactions of Dialkylzinc Reagents to Trifluoromethyl Ketones: Structural Authentication of a -hydride Elimination Product Containing a Tetranuclear Zinc Chain
E. Hevia, A. R. Kennedy, J. Klett, Z. Livingstone, M. D. McCall
Dalton Trans, 2010, 39, 520-526.
https://pubs.rsc.org/en/content/articlelanding/2010/dt/b911818g/unauth#!divAbstract
2009
61. Closer Insight into the Reactivity of TMP-dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates
W. Clegg, B. Conway, E. Hevia, M. D. McCall, L. Russo, R. E. Mulvey
J. Am. Chem. Soc. 2009, 131, 2375-2384.
https://pubs.acs.org/doi/abs/10.1021/ja8087168
60. Donor-dictated Interlocking Co-complexation Reactions of LiNHDipp with Dimethylzinc: Synthesis and Structures of New Methyl(amido)zincates
W. Clegg, D. V. Graham, E. Herd, E. Hevia, A. R. Kennedy, M. D. McCall, L. Russo
Inorg. Chem. 2009, 48, 5320-5327.
https://pubs.acs.org/doi/abs/10.1021/ic900313b
59. Direct lateral Metallation using Alkali-Metal-Mediated Zincation (AMMZn): SiC-H vs Si-O Bond Cleavage
E. Hevia, A. R. Kennedy, J. Klett, M. D. McCall
Chem. Commun. 2009, 3240-3242.
https://pubs.rsc.org/en/content/articlelanding/2009/CC/b903592c#!divAbstract
58. Synthetic and Structural Insights into the Zincation of Toluene: Direct Synergic Ring Metalation vs Indirect Non-synergic Lateral Metalation
D. R. Armstrong, J. García-Álvarez, D. V. Graham, G. W. Honeyman, E. Hevia, A. R. Kennedy, R. E. Mulvey
Chem. Eur. J, 2009, 15, 3800-3807.
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.200801928
57. Contacted ion-pair lithium alkylamidoaluminates: intramolecular alumination (Al-H exchange) traps for TMEDA and PMDETA
B. Conway, J. García-Álvarez, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. D. Robertson
Organometallics, 2009, 28, 6462-6468.
https://pubs.acs.org/doi/abs/10.1021/om900736a
56. Synergic Synthesis of Benzannulated Zincabicyclic Complexes, -Zincated N Ylides, through Sodium TMEDA-Mediated Zincation of a Haloarene
D. R. Armstrong, L. Balloch, W. Clegg, S. H. Dale, P. García-Álvarez, E. Hevia, L. M. Hogg, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara
Angew. Chem. Int. Ed. 2009, 48, 8675-8678.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200904506
55. Structurally Defined Potassium-Mediated Zincation of Pyridine and 4-R-Substituted Pyridines (R=Et, iPr, tBu, Ph and Me2N) by Using Dialkyl-TMP-Zincate Bases
W. Clegg, B. Conway, D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey, L. Russo, D. S. Wright
Chem. Eur. J. 2009, 15, 7074-7082.
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.200900549#
2008
54. Synthesis and Structural Elucidation of Alkyl, Amido and Mixed Alkyl-Amido “Highly-Coordinated” Zincates
D. R. Armstrong, C. Dougan, D. V. Graham, E. Hevia, A. R. Kennedy
Organometallics, 2008, 27, 6063-6070.
https://pubs.acs.org/doi/abs/10.1021/om800786n
53. Metalation of 2, 4, 6-Trimethylacetophenone using Organozinc Reagents
D. R. Armstrong, A. M. Drummond, L. Balloch, D. V. Graham, E. Hevia, A. R. Kennedy
Organometallics, 2008, 27, 5860-5866.
https://pubs.acs.org/doi/abs/10.1021/om800658s
52. Synthesis and Structural Elucidation of Solvent-Free and Solvated Lithium Dimethyl(HMDS)zincates
D. R. Armstrong, E. Herd, D.V. Graham, E. Hevia,A. R. Kennedy, W. Clegg, L. Russo
Dalton Trans. 2008, 1323-1330.
https://pubs.rsc.org/en/content/articlelanding/2008/dt/b716494g/unauth#!divAbstract
51. Transamination Chemistry of Sodium TMP-zincate: Synthesis and Crystal Structure of a Chiral Amidozincate
D. R. Armstrong, W. Clegg, S. H. Dale, J. García-Álvarez, R. W. Harrington, E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara
Chem. Commun. 2008, 187-189.
https://pubs.rsc.org/en/content/articlelanding/2008/cc/b713987j#!divAbstract
50. Unmasking Representative Structures of TMP-Active Hauser and Turbo Hauser Bases
P. García-Álvarez, D. V. Graham, E. Hevia, A. R. Kennedy, J. Klett, R. E. Mulvey, C. T. O’Hara, S. Weatherstone
Angew. Chem. Int. Ed. 2008, 47, 8079-8081.
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.200802618
49. Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA= diisopropylamide) with Phenylacetylene
W. Clegg, J. García-Álvarez, P. García-Álvarez, D. V. Graham, R. W. Harrington, E. Hevia, A. R. Kennedy, R. E. Mulvey, L. Russo
Organometallics. 2008, 27, 2654-2663.
https://pubs.acs.org/doi/abs/10.1021/om8001813
48. Structurally-defined Potassium-Mediated Regioselective Zincation of Amino-and Alkoxy Substituted Pyridines
B. Conway, D. V. Graham, E. Hevia, A. R. Kennedy, J. Klett, R. E. Mulvey
Chem. Commun. 2008, 2638-2640.
https://pubs.rsc.org/en/content/articlelanding/2008/CC/b805606d#!divAbstract
47. Synthesis and Characterisation of New Bimetallic Alkali Metal-Magnesium Mixed Diisopropylamide-Acetylides: Structural Variations in Bimetallic Lithium- and Sodium-Heteroleptic Magnesiates
J. García-Álvarez, D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey
Dalton Trans. 2008, 1481-1486.
https://pubs.rsc.org/en/content/articlelanding/2008/DT/b716215d#!divAbstract
46. Alkali-Metal-Mediated Manganation(II) of Functionalized Arenes and Applications of Ortho-Manganated Products in Pd-Catalyzed Cross-Coupling Reactions with Iodobenzene
V. L. Blair, W. Clegg, B. Conway, E. Hevia, A. Kennedy, J. Klett, R. E. Mulvey, L. Russo
Chem. Eur. J. 2008, 14, 65-72.
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.200701597
45. Structurally-Defined Reactions of Sodium TMP-Zincate with Nitrile Compounds:Synthesis of a Salt-like Sodium Sodiumdizincate and Other Unexpected Ion Pair Products
W. Clegg, S. H. Dale, E. Hevia, L. M. Hogg, G. W. Honeyman, R. E. Mulvey, C. T. O’Hara, L. Russo
Angew. Chem. Int. Ed. 2008, 47, 731-734.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200704341
2007
44. Structurally-Defined Direct C-Magnesiation and C-Zincation of N-Heterocyclic Aromatic Compounds using Alkali-Metal-Mediated Metallation
B. Conway, E. Hevia, A. R. Kennedy, R. E. Mulvey
Chem. Commun. 2007, 2864-2866.
https://pubs.rsc.org/en/content/articlelanding/2007/CC/b704362g#!divAbstract
43. Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry
B. Conway, E. Hevia, J. García-Álvarez, D. V. Graham, A. R. Kennedy, R. E. Mulvey
Chem. Commun. 2007, 5241-5243.
https://pubs.rsc.org/en/content/articlelanding/2007/cc/b713913f#!divAbstract
42. Lewis base stabilized lithium TMP – aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane
J. Garcia-Alvarez, E. Hevia, A. R. Kennedy, J. Klett, R. E. Mulvey
Chem. Commun. 2007, 2402-2404.
https://pubs.rsc.org/en/content/articlelanding/2007/cc/b700785j/unauth#!divAbstract
41. Synthesis of Mixed Alkali Metal-Zinc Enolate Complexes Derived from 2, 4, 6-Trimethylacetophenone: New Inverse Crown Structures
S. H. Baillie, E. Hevia, A. R. Kennedy, R. E. Mulvey
Organometallics, 2007, 26, 204-209.
https://pubs.acs.org/doi/abs/10.1021/om060878k
40. Structural Variations in Bimetallic Sodium-Magnesium and Sodium-Zinc Ketimides, and a Sodium-Zinc Alkide-Alkoxide-Amide: Connections to Ring-Stacking, Ring-Laddering, and Inverse Crown Concepts
W. Clegg, S. H. Dale, D. V. Graham, R. W. Harrington, E. Hevia, L. M. Hogg, A. R. Kennedy, R. E. Mulvey
Chem. Commun. 2007, 1641-1643.
https://pubs.rsc.org/en/content/articlelanding/2007/CC/b618609b#!divAbstract
39. Dizincation and Dimagnesiation of Benzene using Alkali-Metal-Mediated Metallation
D. R. Armstrong, W. Clegg, S. H. Dale, D. V. Graham, E. Hevia, L. M. Hogg, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey
Chem. Commun. 2007, 598-600.
https://pubs.rsc.org/en/content/articlelanding/2007/cc/b613655a#!divAbstract
2006
38. Lithium Dimethyl-amidozinc Complexes: Contrasting Zincate (Amido = TMP) and Inverse Zincate (Amido = HMDS) Structures on Addition of TMEDA
D. V. Graham, E. Hevia, A.R. Kennedy, R. E. Mulvey
Organometallics, 2006, 25, 3297-3300.
https://pubs.acs.org/doi/abs/10.1021/om060334i
37. Synthesis and Reactivity of New(Methoxy)methyl Complexes of Manganese(I) and Rhenium(I)
E. Hevia, D. Miguel, J. Pérez, V. Riera
Organometallics, 2006, 25, 4909-4912.
https://pubs.acs.org/doi/abs/10.1021/om060459n
36. Synergic Para-Directed-Monometalation of Bis(toluene)chromium by using Alkali-Metal-Mediated Magnesiation
P. C. Andrikopoulos, D. R. Armstrong, E. Hevia, A. R. Kennedy, R. E. Mulvey
Organometallics, 2006, 25, 2415-2418.
https://pubs.acs.org/doi/abs/10.1021/om060216v
35. Synthesis and Characterization of New Mixed-Metal Sodium-Magnesium Enolates Derived from 2,4, 6-Trimethylacetophenone
E. Hevia, K. W. Henderson, A. R. Kennedy, R. E. Mulvey
Organometallics, 2006, 25, 1778-1785.
https://pubs.acs.org/doi/abs/10.1021/om051076c
34. Electronic Structure and Excited States of Rhenium(I) Amido and Phosphido Carbonyl-Bipyridine Complexes Studied by Picosecond Time-Resolved IR Spectroscopy and DFT Calculations
A. Grabrielsson, M. Busby, P. Matousek, MI. Towrie, E. Hevia, L. Cuesta, J. Perez, S. Zalis, A. Vlcek, Jr
Inorg. Chem. 2006, 45, 9789-9797.
https://pubs.acs.org/doi/abs/10.1021/
33. Alkali-Metal-Mediated Zincation of Polycyclic Aromatic Hydrocarbons: Synthesis and Structures of Monozincated and Dizincated Naphthalenes
W. Clegg, S. H. Dale, E. Hevia, L. M: Hogg, G. W. Honeyman, R. E. Mulvey, C. T. O´Hara
Angew. Chem. Int. Ed. 2006, 45, 6548-6550.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200602288
32. Alkali-Metal-Mediated Zincation of Anisole: Synthesis and Structures of Three Instructive Ortho-Zincated Complexes
W. Clegg, S. H. Dale, E. Hevia, G. W. Honeyman, R. E. Mulvey
J. Am. Chem. Soc. 2006, 128, 7434-7435.
https://pubs.acs.org/doi/abs/10.1021/ja061898g
31. Directed Meta-Metalation Using Alkali-Metal-Mediated Zincation
D. R. Armstrong, W. Clegg, S. H. Dale, E. Hevia, L. M. Hogg, G. W. Honeyman, R. E. Mulvey
Angew. Chem. Int. Ed. 2006, 45, 3775-3778.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200600720
30. Reactivity of Molybdenum and Rhenium Hydroxo Complexes toward Organic Electrophiles: Reactions that Afford Carboxylato Products
L. Cuesta, E. Hevia, D. Morales, J. Pérez, L. Riera, D. Miguel
Organometallics, 2006, 25, 1717-1722.
https://pubs.acs.org/doi/abs/10.1021/om051081g
29. Pre-Metalation Insights into the Use of Alkali-Metal-Mediated Zincation for Directed ortho Metalation of a Tertiary Aromatic Amide
W. Clegg, S. H. Dale, E. Hevia, G. W. Honeyman, R. E. Mulvey
Angew. Chem. Int. Ed. 2006, 45, 2370-2374.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200503202
28. Post-Metalation Insights into the Use of Alkali-Metal-Mediated Zincation for Directed ortho-Metalation of a Tertiary Aromatic Amide
W. Clegg, S. H. Dale, R. W. Harrington, E. Hevia, G. W. Honeyman, R. E. Mulvey
Angew. Chem. Int. Ed. 2006, 45, 2374-2377.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200503213
27. Building an Extended Inverse Crown Motif via Alkali-Metal-Mediated -Magnesation of Furan
D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, Christine Talmard
Chem. Commun. 2006, 417.
https://pubs.rsc.org/en/content/articlelanding/2006/CC/b514985a#!divAbstract
2005
26. Trapping, Stabilization, and Characterization of an Enolate Anion of a 1, 6 – Adduct of Benzophenone Chelated by a Sodium Alkylamidozincate Cation
E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey
J. Am. Chem. Soc. 2005, 127, 13106-13107.
https://pubs.acs.org/doi/abs/10.1021/ja053756c
25. Alkali-Metal–Mediated Zincation of Ferrocene: Synthesis, Structure, and Reactivity of a New Lithium TMP-Zincate Reagent
H. R. L. Barley, William Clegg, S. H. Dale, E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey
Angew. Chem. Int. Ed., 2005, 44, 6018-6021.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200501560
24. Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions
P. C. Andrikopoulos, D. R. Armstrong, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara
Chem. Commun. 2005, 1131-1133.
https://pubs.rsc.org/en/content/articlelanding/2005/CC/b416636a#!divAbstract
23. Sodium Dialkyl-amidozincates, Alkyl or Amido Bases? An Experimental and Theoretical Case Study
P. C. Andrikopoulos, D. R. Armstrong, H. R. L. Barley, W. Clegg, S. H. Dale, E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey
J. Am. Chem. Soc. 2005, 127, 6184-6186.
https://pubs.acs.org/doi/10.1021/ja050860l
22. Selective Meta-Deprotonation of Toluene Using Alkali Metal-Mediated Magnesiation.
P. C. Andrikopoulos, D. R. Armstrong, D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, C. Talmard
Angew. Chem. Int. Ed. 2005, 44, 3459-3462.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200500379
21. Synthesis and characterization of a series of alkylmagnesium amide and related oxygen-contaminated alkoxy compounds
B. Conway, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. Weatherstone
Dalton Trans. 2005, 1532-1544.
https://pubs.rsc.org/en/content/articlelanding/2005/DT/b501502b#!divAbstract
20. Activation of ancillary ligands in the reactions of DMAD with phosphido and alkylidenamido rhenium complexes
L. Cuesta, E. Hevia, D. Morales, J. Pérez, V. Riera, M. Seitz, D. Miguel
Organometallics 2005, 24, 1772-1775.
https://pubs.acs.org/doi/abs/10.1021/om049019r
19. Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex
L. Cuesta, E. Hevia, D. Morales, J. Pérez, V. Riera, E. Rodríguez, D. Miguel
Chem. Commun. 2005, 116-117.
https://pubs.rsc.org/en/content/articlelanding/2005/cc/b412447b#!divAbstract
18. Synergic monodeprotonation of bis(benzene)chromium using mixed alkali metal-magnesium amide bases and structural characterization of the heterotrimetallic products
E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey, D. C. Sherrington
Angew. Chem. Int. Ed. 2005, 44, 68-72.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200460637
2004
17. Isolation and characterization of the heterometallic sodium-magnesium mixed monoalkyl-bisamido complex [Na(-Bu)(-TMP)Mg(TMP).(TMEDA)]: chelate-trapping of a surprising intermediate in the formation ofinverse crowns
E. Hevia, D. J. Gallagher, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, C. Talmard
Chem. Commun. 2004, 2422-2423.
https://pubs.rsc.org/en/content/articlelanding/2004/cc/b410293b#!divAbstract
16. A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via mixed sodium-magnesium tris(diisopropylamide) synergic base
P. C. Andrikopoulos, D.R. Armstrong, W. Clegg, C. J. Gilfillan, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, J.A. Parkinson, D. M. Tooke
J. Am. Chem. Soc. 2004, 126, 11612-11620.
https://pubs.acs.org/doi/abs/10.1021/ja0472230
15. Synthesis and crystal structure of [{nBuMg(-TMP)2}] and of a homometallic inverse crown in tetranuclear [{nBuMg2[-N(H)Dipp]2(3-OnBu)}2]
E. Hevia, A. R. Kennedy, R. E. Mulvey, S. Weatherstone
Angew. Chem. Chem. Int. Ed. 2004, 43, 1709-1712.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200353286
14. Reactivity of Molybdenum and Rhenium hydroxo-carbonyl complexes toward organic electrophiles
L. Cuesta, D. C. Gerbino, E. Hevia,D. Morales, M. E. Navarro Clemente, J. Pérez, L. Riera, V. Riera, D. Miguel, I. Del Rio, S. Garcia-Granda
Chem. Eur. J. 2004, 10, 1765-1777.
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.200305577
2003
13. Solvent-free and TMEDA-solvated mixed alkali metal-magnesium tris-diisopropylamides
E. Hevia, F. R. Kenley, A. R. Kennedy, R. E. Mulvey, R. B. Rowlings
Eur. J. Inorg. Chem. 2003, 3347-3353.
https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200300413
12. Synthesis of -lactams from a N-rhenaimine: effect of the transition metal on the energetic profile of the Staudinger reaction
E. Hevia, J. Pérez, V. Riera, D. Miguel, M. I. Menéndez, T. L. Sordo, S. García-Granda
J. Am. Chem. Soc. 2003, 125, 3706-3707.
https://pubs.acs.org/doi/abs/10.1021/ja034070s
11. Mono and dimetallic cyanocomplexes with {Mo(3-allyl)(CO)2(N-N)} fragments
J. Pérez, E. Hevia, L. Riera, V. Riera, S. García-Granda, E. García-Rodríguez, D. Miguel
Eur. J. Inorg. Chem. 2003, 1113-1120.
https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200390142
10. A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide
D. Gerbino, E. Hevia, D. Morales, M. E. Navarro Clemente, J. Pérez, L. Riera, V. Riera, D. Miguel
Chem. Commun. 2003, 328-329.
https://pubs.rsc.org/en/content/articlelanding/2003/CC/b210860g#!divAbstract
9. Reactivity of the amido complex [Re(NHpTol)(CO)3(bipy)] toward neutral organic electrophiles
E. Hevia, J. Pérez, V. Riera, D. Miguel
Organometallics 2003, 22, 257-263.
https://pubs.acs.org/doi/abs/10.1021/om020667p
2002
8. Manganese (I) and rhenium (I) tricarbonyl (alkylthio)methyl and alkylidenesulfonium complexes
E. Hevia, J. Pérez, V. Riera, D. Miguel
Organometallics 2002, 21, 5312-5319.
https://pubs.acs.org/doi/abs/10.1021/om020522i
7. Insertion and cycloaddition reactivity of a transition-metal N-metalloimine
E. Hevia, J. Pérez, V. Riera, D. Miguel
Angew. Chem. Int. Ed. 2002, 41, 3858-3860.
https://onlinelibrary.wiley.com/doi/abs/10.1002/
6. Insertion of Unsaturated Organic Electrophiles into Molybdenum-Alkoxide and Rhenium-Alkoxide Bonds of Neutral, Stable Carbonyl Complexes
E. Hevia, J. Pérez, L. Riera,V. Riera, I. Del Río, S. García-Granda, D. Miguel
Chem. Eur. J. 2002, 8, 4510-4521.
5. Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)3(bipy)] (R = H or Me): N-H vs. Re-N
E. Hevia, J. Pérez, V. Riera, D. Miguel
Chem. Comun. 2002, 1814-1815.
https://pubs.rsc.org/en/content/articlelanding/2002/cc/b203261a/unauth#!divAbstract
4. New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands
E. Hevia, J. Pérez, V. Riera, D. Miguel, S. Kassel, A. Rheingold
Inorg. Chem. 2002, 41, 4673-4679.
https://pubs.acs.org/doi/abs/10.1021/ic020174c
3. New octahedral rhenium (I) tricarbonyl amido complexes
E. Hevia, J. Pérez,V. Riera, D. Miguel
Organometallics 2002, 21, 1966-1974.
https://pubs.acs.org/doi/abs/10.1021/om0110383
2. Reactive Alkoxide Complexes of Groups 6 and 7 Metals
E. Hevia, J. Pérez, L. Riera, V. Riera, D. Miguel
Organometallics 2002, 21, 1750-1752.
https://pubs.acs.org/doi/abs/10.1021/om010977s
2001
1. Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorus oxoanions
L. T. Burke, E. Hevia-Freire, R. Holland, J. C. Jeffery, A. P. Leedham, C. A. Russell, A. Steiner, A. Zagorski
Chem. Comun. 2000, 1769-1770.
https://pubs.rsc.org/en/content/articlelanding/2000/CC/b004192k#!divAbstract