Publications
2025
212. Assessing Coordination of Organic π-Acceptors to Alkali-Metal Nickelates
L. Vedani, E. Hevia
Chimia, 2025, 79, 869.
https://www.chimia.ch/chimia/article/view/2025_869/2025_869
211. Highly-Reduced Alkali-Metal Nickelates: Synthesis, Structure, Catalytic Applications and Alkali-Metal Effects
L. Vedani, A. M. Borys, K. Rachuy, R. Herbst-Irmer, D. Stalke, E. Hevia
J. Am. Chem. Soc. 2025, 147, 46101
https://pubs.acs.org/doi/full/10.1021/jacs.5c14047
210. Upgrading Sodium-Mediated Deprotonative Borylation to Catalytic Regimes: Regioselective Control and Mechanistic Implications
C. Tan, A. Tortajada, A. McGinley, M. Mu, Max García-Melchor, E. Hevia
J. Am. Chem. Soc. 2025, 147, 42076.
https://doi.org/10.1021/jacs.5c15994
209. Assessing Sodium Amide Reagents for Ester Amidations in Deep Eutectic Solvents in Continuous Flow
A. W. J. Platten, B. Pinho, L. Torrente-Murciano. E. Hevia
ACS Sustainable Chem. Eng. 2025, 13, 44, 19351
https://doi.org/10.1021/acssuschemeng.5c08775
208. Are Grignard Reactions in Deep Eutectic Solvents Interface-Driven?
I. Manasi, M. Bortoli, D. T. Bowron, M. Campana, O. S. Hammond, T. F. Headen, J. Hooton, E. Hevia, M. Cascella, O. Eisenstein, K. J. Edler
Angew. Chem. Int. Ed. 2025, 64, e202513649
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202513649
207. Synthesis and Structure of Neopentyl Sodium: A Hydrocarbon-Soluble Reagent for Controlled Sodiation of Non-Activated Substrates
D. E. Anderson, L. Malaspina, S. Grabowsky, E. Hevia
Angew. Chem. Int. Ed. 2025, 64, e202511492
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202511492
206. Structurally Mapping Sodium-mediated Synthesis of 1,4-substituted dihydropyridines: Nucleophilic Addition vs Deprotonative Metalation
D. Sanchez Roa , J. Kocher , A. Tortajada , E. Hevia
Synthesis, 2025, early view
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/a-2651-2367
205. Structural and Mechanistic Insights into the Metalation of Fluoroarenes Mediated by a Superbasic Co(II) Bis(amide) Complex
N. Jin, E. Hevia
Chimia, 2025, 79, 224
https://www.chimia.ch/chimia/article/view/2025_224/2025_224
204. Magnesium Nickelate Complexes and Their Implications in Ni-Catalyzed Cross-Couplings of Aryl Fluorides and Aryl Ethers with Grignard Reagents
L. Vedani, A. M. Borys, E. Hevia
Inorg. Chem. 2025, 64, 16, 8354
https://pubs.acs.org/doi/10.1021/acs.inorgchem.5c00755
203. Iron-catalysed direct coupling of organosodium compounds
I. Takahashi, A.Tortajada, D. E. Anderson, L. Ilies, E. Hevia, S. Asako
Nat. Synth. 2025, 4, 816
https://www.nature.com/articles/s44160-025-00771-1
202. Biphenylene Coordination and Ring-Opening by Alkali-Metal Nickelates
A. M. Borys, A. E. F. Denjean, L. Vedani, D. Balcells, E. Hevia
Angew, Chem. Int. Ed. 2025, 64, e202501995
https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202501995
201. Harnessing Organopotassium Reagents for Cross-Coupling with YPhos-Pd Catalysts: Opportunities, Applications, and Challenges
D. Knyszek, J.Löffler, D. E. Anderson, E. Hevia, V. H. Gessner
J. Am. Chem. Soc. 2025, 147, 5417.
https://pubs.acs.org/doi/full/10.1021/jacs.4c18073
200. Selective Hydrogen Isotope Exchange Catalysed by Simple Alkali-Metal Bases in DMSO
M. S. Tschopp, A. Tortajada, E. Hevia
Angew, Chem. Int. Ed. 2025, 64, e202421736
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202421736
199. Harnessing Deep Eutectic Solvents for Regioselective Polar Additions to α,β-Unsaturated Ketones and Aldehydes
A. W. J. Platten, I. Manasi, M. Campana, K. J. Edler, E. Hevia
ChemSusChem 2025, 18, e202402083
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202402083
198. Structural and Reactivity Implications of Homo and Heterobimetallic Co(II) Amides Prepared via Trans(amination) Reactions
N. Jin, A. Logallo, E. Hevia
Organometalllics, 2025, 4, 197
https://pubs.acs.org/doi/abs/10.1021/acs.organomet.4c00425
197. Room Temperature Intermolecular Hydroamination of Vinylarenes Catalyzed by Alkali-Metal Ferrate Complexes
A. Tortajada, E. Hevia
ACS Org. Inorg. Au, 2025, 5, 62
https://pubs.acs.org/doi/full/10.1021/acsorginorgau.4c00066
2024
196. Unveiling the Structural Complexity of Lithium Organozinc Alkoxo Clusters and their Applications to Enantioselective Michael Addition Reactions
M. Dell’Aera, F. Maria Perna, P. Vitale, A. Altomare, E. Hevia, V. Capriati
Eur. J. Inorg. Chem. 2024, 27, e202400505
https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202400505
195. Alkali-Metal Nickelates: Catalytic Cross-Coupling, Clusters and Coordination Complexes
A. M. Borys, E. Hevia
Chem Comm. 2024, 60, 11052.
https://pubs.rsc.org/en/content/articlepdf/2024/cc/d4cc03548h
194. Combining two relatively weak bases (Zn(TMP)2 and KOtBu) for the regioselective metalation of non-activated arenes and heteroarenes
N. R. Judge, E. Hevia
Chem. Sci. 2024, 15, 14757
https://pubs.rsc.org/en/content/articlepdf/2024/sc/d4sc03892d
193. Reductive-Transmetalation Reactions of ZnR2/(AlCp*)4 Heterobimetallic Combinations and Application towards CO2 Insertion
E. Hevia, F. Dankert
Eur. J. Inorg. Chem. 2024, 27, e202400418
https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202400418
192. Investigating Reductive Elimination and Ligand Exchange Pathways from Homoleptic Lithium Nickelate Acetylide Complexes
A. M. Borys, L. Vedani, E. Hevia
Organometallics, 2024, 43, 24, 3171
https://pubs.acs.org/doi/full/10.1021/acs.organomet.4c00181
191. Alkene Isomerisation Catalysed by a Superbasic Sodium Amide
A. Tortajada, G. L. Righetti, A.McGinley, M. Mu, M. García-Melchor, E.Hevia
Angew. Chem. Int. Ed. 2024, 63, e202407262
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202407262
190. Dual Basicity and Nucleophilicity of Organosodium Reagents in Benzylic C-H Additions of Toluenes to Diarylethenes and Ketones
D. E. Anderson, A. Truong, E. Hevia
Chem. Eur. J. 2024, 30, e202400492
https://doi.org/10.1002/chem.202400492
189. Development of Sterically Hindered and Basic Sodium Amides for Catalytic Hydrogen Isotope Exchange
M. S. Tschopp, A. W.J. Platten, E. Hevia, A. Tortajada
Eur. J. Inorg. Chem. 2024, 27, e202400200
https://doi.org/10.1002/ejic.202400200
188. Tuning NaCo(II) Bimetallic Cooperativity to Perform Co–H Exchange / C–F Bond Activation Processes in Polyfluoroarenes
A. Logallo, E. Hevia,
Chimia 2024, 78, 238
https://doi.org/10.2533/chimia.2024.238
187. The coordination of alkali-metal nickelates to organic π-systems: Synthetic, structural and spectroscopic insights
A. M. Borys, L. Vedani, E Hevia
Dalton Trans. 2024, 53, 8382
https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt00889h
186. Unlocking the Metalation Applications of TMP-powered Fe and Co(II) bis(amides): Synthesis, Structure and Mechanistic Insights
A. Logallo, L. C. H. Maddock, M. Mu, L. Gravogl, N. Jin, M. N. Peñas-Defrutos, K. Meyer,M. García-Melchor, E. Hevia
Angew. Chem. Int. Ed. 2024, 63, e202402907
https://onlinelibrary.wiley.com/doi/10.1002/anie.202402907
185. Stoichiometric and Catalytic Lithium Nickelate-Mediated C–F Bond Alkynylation of Fluoroarenes
A. M. Borys, L. Vedani, E Hevia
J. Am. Chem. Soc. 2024, 146, 10199
https://pubs.acs.org/doi/10.1021/jacs.4c02606
184. Enhancing the Metalating Power of ZnEt2 via Formation of an Alkyl/Alkoxide Potassium Zincate
J. Kocher, N. R. Judge, E. Hevia
Helv.Chim. Acta, 2024, 107, e202300237
https://doi.org/10.1002/hlca.202300237
183. Synthesis and Modular Reactivity of Low Valent Al/Zn Heterobimetallics Supported by Common Monodentate Amides
F. Dankert, E.Hevia
Chem. Eur. J. , 2024, 30, e202304336
https://doi.org/10.1002/chem.202304336
182. New Frontiers in Organosodium Chemistry as Sustainable Alternatives to Organolithium Reagents
D. A. Anderson, A. Tortajada, E. Hevia
Angew. Chem. Int. Ed. 2024, 63, e202313556
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202313556
2023
181. Main Group Metal Strategies for C–H and C–F Bond Activation and Functionalisation of Fluoroarenes
N.R. Judge, A. Logallo, E. Hevia
Chem. Sci. 2023, accepted artcle
https://pubs.rsc.org/en/content/articlelanding/2023/sc/d3sc03548d
180. Shedding Light on the Hidden Roles of Lithium in the Nickel-Catalyzed Cross-Coupling of Aryl Ethers
H. Liang, A. Borys, E. Hevia, M. E. Perrin, P. A. Payard
J. Am. Chem. Soc. 2023, 145, 19989
https://pubs.acs.org/doi/abs/10.1021/jacs.3c06647
179. Interaction and energy decomposition analyses to predict stability of tetraaryl square planar cobalt complexes
M. Mu, Al. Logallo, E. Hevia, M. Garcia-Melchor
ChemCatChem 2023, 15 e202300769
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202300769
178. Alkali-Metal Bases in Catalytic Hydrogen Isotope Exchange Processes
A. Tortajada, E. Hevia
Catal. Sci. Technol. 2023, 13, 4919
https://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00825H
177. Atom-efficient arylation of N-tosylimines mediated by cooperative ZnAr2/Zn(C6F5)2 combinations
A. M. Borys, T. Kunzmann, E. Hevia
Chem. Commun. 2023, 59, 7583.
https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc01490h
176. Sodium Mediated Deprotonative Borylation of Arenes Using Sterically Demanding B(CH2SiMe3)3: Unlocking Polybasic Behaviour and Competing Lateral Borane Sodiation
A. Tortajada, L. J. Bole, M. Mu, M. Stanford, M. N. Peñas-Defrutos, M. García-Melchor, E. Hevia
Chem. Sci. 2023, 14, 6538
https://pubs.rsc.org/en/content/articlelanding/2023/sc/d3sc01705b
175. Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
A. M. Borys, E. Hevia
Chem. Commun. 2023, 59, 7032
https://pubs.rsc.org/en/Content/ArticleLanding/2023/CC/D3CC01729J
174. Uncovering the Untapped Potential of the Use of Sodium Amides for Regioselective Arene Functionalisation
A. Tortajada, E. Hevia
Chimia, 2023, 77, 225
https://doi.org/10.2533/chimia.2023.225
173. New Frontiers in Alkali-Metal Nickelates
A. M. Borys, E. Hevia
Chimia, 2023, 77, 242
https://doi.org/10.2533/chimia.2023.242
172. Applying Na/Co(II) Bimetallic Partnerships to Promote Multiple Co–H Exchanges in Polyfluoroarenes
A. Logallo, E. Hevia
Chem. Commun., 2023, 59, 5383
171. Alkali-Metal-Alkoxide Powered Zincation of Fluoroarenes Employing Zinc Bis-Amide Zn(TMP)2
N. Judge, E. Hevia
Angew. Chem. Int. Ed. 2023, 62, e202303099
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202303099
170. Structural and synthetic insights on oxidative homocouplings of alkynes mediated by alkali-metal manganates
P. Mastropierro, A. W. J. Platten, A. R. Kennedy, E. Hevia, M. Uzelac
Chem. Eur. J, 2023, 29, e202300593
https://doi.org/10.1002/chem.202300593
169. Structural and synthetic insights into the chemistry of lithium tetraorganozincates
A. M. Borys, M. Dell’Aera, V. Capriati, E. Hevia
Adv. Organomet. Chem 2023, 80, 1
https://doi.org/10.1016/bs.adomc.2022.11.001
168. Highly Reactive Hydrocarbon Soluble Alkylsodium Reagents for Benzylic Aroylation of Toluenes using Weinreb Amides
D. E. Anderson, A. Tortajada, E. Hevia
Angew. Chem. Int. Ed. 2023, 62, e202218498
https://doi.org/10.1002/anie.202218498
167. Diphenylacetylene Stabilised Alkali-Metal Nickelates: Synthesis, Structure and Catalytic Applications
A. M. Borys, E. Hevia,
Dalton Trans. 2023, 52, 2098
https://doi.org/10.1039/D3DT00069A
2022
166. Continuous, stable, and safe organometallic reactions in flow at room temperature assisted by deep eutectic solvents
F. F. Mulks, B. Pinho, A. W.J. Platten, M. R. Andabili, A. J. Expósito, K. J. Edler, E. Hevia, L. Torrente-Murciano
Chem 2022, 8, 3382.
https://doi.org/10.1016/j.chempr.2022.11.004
165. Building Square Planar Cobalt (II) Complexes via Sodium Mediated Cobaltation of Fluoroarenes
A. Logallo, M. Mu, M. García-Melchor, E. Hevia
Angew. Chem. Int. Ed. 2022, 134, e202213246
https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202213246
164. Perdeuteration of Arenes via Hydrogen Isotope Exchange Catalyzed by the Superbasic Sodium Amide Donor Species NaTMP·PMDETA
A. Tortajada, E. Hevia
J. Am. Chem. Soc., 2022, 144, 20237
https://pubs.acs.org/doi/abs/10.1021/jacs.2c09778
163. Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX·LiX (X = Cl, Br)
A. Kremsmair, A. S. Sunagatullina, L. J. Bole, P. Mastropierro, S. Graßl, H. R. Wilke, E. Godineau, E. Hevia, P. Knochel
Angew. Chem. Int. Ed. 2022, 61, e202210491
https://onlinelibrary.wiley.com/doi/10.1002/anie.202210491
162. Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent-Induced Dissociation Effects
G. M. Ballmann, T. X. Gentner, A. R. Kennedy, E. Hevia, R. E. Mulvey
Chem. Eur. J. 2022, early view, e202201716
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.202201716
161. Towards Hexagonal Planar Nickel: A Dispersion-Stabilised Tri-Lithium Nickelate
A, M. Borys, L. A. Malaspina, S. Grabowsky, E. Hevia
Angew. Chem. Int. Ed. 2022, 61, e202209797
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202209797
160. Gram-Scale Synthesis, Isolation and Characterisation of Sodium Organometallics: nBuNa and NaTMP
A. Tortajada, D. E. Anderson, E. Hevia
Helv. Chim. Acta, 2022, 105, e202200060
https://onlinelibrary.wiley.com/doi/10.1002/hlca.202200060
159. Enhancing Metalating Efficiency of the Sodium Amide NaTMP in Arene Borylation Applications
L. J. Bole, A. Tortajada, E. Hevia
Angew. Chem. Int. Ed. 2022, 61, e202204262
https://doi.org/10.1002/anie.202204262
158. Alkali Metal Metal(ates) Containing Divalent Earth Abundant Transition Metals
A. Logallo, E. Hevia
Chimia, 2022, 76, 336.
https://doi.org/10.2533/chimia.2022.336
157. Unmasking the constitution and bonding of the proposed lithium nickelate “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand
R. J. Somerville, A. M. Borys, M. Perez-Jimenez, A. Nova, D. Balcells, L. A. Malaspina, S. Grabowsky, E. Carmona, E. Hevia, J. Campos
Chem. Sci. 2022, 13, 5268-5276
https://doi.org/10.1039/D2SC01244H
156. Mechanisms of the Nickel-Catalysed Hydrogenolysis and Cross-Coupling of Aryl Ethers
A. M. Borys, E. Hevia
Synthesis, 2022, 2976-2990
https://www.thieme-connect.com/products/ejournals/abstract/10.1055/a-1806-4513
155. Metallation of Sensitive Fluoroarenes using a Potassium TMP-Zincate Supported by a Silyl(bis)amido Ligand
P. Mastropierro, A. R. Kennedy, E. Hevia
Chem Commun. 2022, 58, 5292
https://doi.org/10.1039/D2CC00979J
154. Activation of polar organometallic reagents with alkali–metal alkoxides
L. J. Bole, E. Hevia
Nature Synthesis, 2022, 1, 195
https://doi.org/10.1038/s44160-022-00040-5
153. Hydrophosphinylation of Styrenes Catalysed by Well-Defined s-Block Bimetallics
A. W. J. Platten, A. M. Borys, E. Hevia
ChemCatChem 2022, 14, e202101853
https://doi.org/10.1002/cctc.202101853
152. Assessing Alkali-Metal Effects in the Structures and Reactivity of Mixed-Ligand Alkyl/Alkoxide Alkali-Metal Magnesiates
N. R. Judge, L. J. Bole, E. Hevia
Chem. Eur. J. 2022, 28, e2021041
https://doi.org/10.1002/chem.202104164
2021
151. Structural and Synthetic Insights into Sodium-Mediated-Ferration of Fluoroarenes
L. C. H. Maddock, A. R. Kennedy, E. Hevia
Helv. Chim. Acta, 2021, 104, e202100206
https://onlinelibrary.wiley.com/doi/10.1002/hlca.202100206
150. Regioselective Synthesis of 1,5-Disubstituted 1,2,3-Triazoles Catalyzed by Cooperative s-Block Bimetallics
M. De Tullio, A. M. Borys, A. Hernán-Gómez, A. R. Kennedy, E. Hevia
Chem Catalysis, 2021, 1, 1308
https://doi.org/10.1016/j.checat.2021.09.016
149. The Anionic Pathway in Nickel-Catalysed Cross-Coupling of Aryl Ethers
A. M. Borys, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 24659.
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202110785
148. Atom-efficient transition-metal-free arylation of N,O-acetals using diarylzinc reagents through Zn/Zn cooperativity
A. M. Borys, J. M. Gil-Negrete, E. Hevia
Chem. Commun. 2021, 57, 8905.
https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc04137a
147. Exploiting chemical cooperativity in main-group bimetallic catalysis
A. M. Borys, E. Hevia
Trends Chem. 2021, 3, 803.
https://doi.org/10.1016/j.trechm.2021.07.006
146. Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilide Ligands
L. C. H. Maddock, R. Morton, A. R. Kennedy, E. Hevia
Chem. Eur. J. 2021, 27, 15181.
https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.202102328
145. Advancing Air- and Moisture-Compatible s-Block Organometallic Chemistry Using Sustainable Solvents
S. E. García-Garrido, A. Presa Soto, E. Hevia, J.García-Álvarez
Eur. J. Inorg. Chem. 2021, 3116.
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100347
Cover Picture: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100601
144. Progressing the Frustrated Lewis Pair Abilities of N-Heterocyclic Carbene/GaR3 Combinations for Catalytic Hydroboration of Aldehydes and Ketones
L. J. Bole, M. Uzelac, A. Hernán-Gómez, A. R. Kennedy, C. T. O’Hara, E.Hevia
Inorg. Chem. 2021, asap article
https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.1c01276
143. Facilitating the Ferration of Aromatic Substrates through Intramolecular Sodium Mediation
L. C. H. Maddock, M. Mu, A. R. Kennedy, M. Garcia-Melchor, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 15296
https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202104275
142. Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS)2] Catalysed Transfer Hydrogenation
T. X. Gentner, E. Hevia, R. E. Mulvey
ChemCatChem. 2021, 13, 2371.
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202100218
141. Untangling the Complexity of Mixed Lithium/Magnesium Alkyl/Alkoxy Combinations Utilised in Br/Mg Exchange Reactions
L. J. Bole, N. R. Judge, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 7626
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202016422
140. Exploiting deprotonative co-complexation to access potassium metal(ates) supported by a bulky silyl(bis)amide ligand
P. Mastropierro, A. R. Kennedy, E. Hevia
Eur. J. Inorg. Chem. 2021, 1016
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202001051
Front Cover: https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202100133
139. Beyond Ni{N(SiMe3)2}2: Synthesis of a Stable Solvated Sodium Tris- Amido Nickelate
A. M. Borys, E. Hevia
Organometallics, 2021, 40, 442
https://pubs.acs.org/doi/abs/10.1021/acs.organomet.0c00785
138. Tandem Mn-I exchange and homocoupling processes mediated by a synergistically operative lithium manganate
M. Uzelac, P. Mastropierro, M. de Tullio, I. Borilovic, M. Tarres, A. R. Kennedy, G. Aromí, E. Hevia
Angew. Chem. Int. Ed. 2021, 60, 3247
https://onlinelibrary.wiley.com/doi/10.1002/anie.202013153
137. Main Group Bimetallic Partnerships for Cooperative Catalysis
J. M. Gil-Negrete, E. Hevia
Chem. Sci. 2021, 12, 1982 DOI;10.1039/d0sc05116k
https://doi.org/10.1039/D0SC05116K
136. Regioselective Bromine/Magnesium‐Exchange for Selective Functionalization of Polyhalogenated Aromatics and Heterocycles
A. Desaintjean, T. Haupt, L. J. Bole, N. R. Judge, E. Hevia, P. Knochel
Angew. Chem. Int. Ed. 2021, 60, 1513
https://doi.org/10.1002/anie.202012496
2020
135. Lithium-mediated Ferration of Fluoroarenes
L.C. H. Maddock. A. R. Kennedy, E. Hevia
CHIMIA, 2020, 74, 866.
https://doi.org/10.2533/chimia.2020.866
134. Towards a Paradigm Shift in Polar Organometallic Chemistry
E. Hevia
CHIMIA, 2020, 74, 681.
https://doi.org/10.2533/chimia.2020.681
133. Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali-Metal Amides under Air
F. F. Mulks, L. J. Bole, L. Davin, A. Hernán-Gómez, A. R. Kennedy, J. García-Álvarez, E. Hevia
Angew. Chem. Int. Ed. 2020, 59, 19021
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202008512
132. Combination of Organocatalytic Oxidation of Alcohols and Highly-Polar Organometallic Chemistry (RLi) in Aqueous Media, at Room Temperature and Under Aerobic Conditions
D. Elorriaga, M. J. Rodríguez-Álvarez, N. Ríos-Lombardía, F. Morís, A. Presa Soto, J. González-Sabín, E. Hevia, J. García-Álvarez
Chem. Commun., 2020, 56, 8932
https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc03768k#!divAbstract
131. Structurally Mapping Alkyl and Amide Basicity in Zincate Chemistry: Di-versity in the Synthesis of Mixed Sodium-Zinc Complexes and their Ap-plications in Enolate Formation
P. Mastropierro, Z. Livingstone,.S. D. Robertson,. A. R. Kennedy, E. Hevia
Organometallics, 2020, 39, 23, 4273 doi: 10.1021/acs.organomet.0c00339
https://pubs.acs.org/doi/abs/10.1021/acs.organomet.0c00339
130. Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents
M. Fairley, L. J. Bole, F. F. Mulks, L. Main, A. R. Kennedy, C. T. O’Hara, J. Garcia-Alvarez, E. Hevia.
Chem. Sci., 2020, 11, 6500
https://pubs.rsc.org/en/content/articlehtml/2020/sc/d0sc01349h
129. A regioselectively 1,1’,3,3’-tetrazincated ferrocene complex displaying core and peripheral reactivity
G. W. Honeyman, D. R. Armstrong, W. Clegg, E. Hevia, A. R. Kennedy, D. L. Ramsay, R. E. Mulvey, J. A. Parkinson, S. A. Orr, R. McLellan, S. D. Robertson, S. Towie.
Chem. Sci. 2020, 11, 6510
https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc01612h#!divAbstract
128. Boosting Conjugate Addition to Nitroolefins Using Lithium Tetraorganozincates: Synthetic Strategies and Structural Insights.
M. Dell’Aera, F. M. Perna, P. Vitale, A. Altomare, A. Palmieri, L. C. H. Maddock, L. J. Bole, A. R. Kennedy, E. Hevia, V. Capriati.
Chem. Eur. J. 2020, 26, 8742
https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.202001294