Publications
2022
166. Continuous, stable, and safe organometallic reactions in flow at room temperature assisted by deep eutectic solvents
F. F. Mulks, B. Pinho, A. W.J. Platten, M. R. Andabili, A. J. Expósito, K. J. Edler, E. Hevia, L. Torrente-Murciano
Chem 2022, 8, 3382.
https://doi.org/10.1016/j.chempr.2022.11.004
165. Building Square Planar Cobalt (II) Complexes via Sodium Mediated Cobaltation of Fluoroarenes
A. Logallo, M. Mu, M. García-Melchor, E. Hevia
Angew. Chem. Int. Ed. 2022, 134, e202213246
https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202213246
164. Perdeuteration of Arenes via Hydrogen Isotope Exchange Catalyzed by the Superbasic Sodium Amide Donor Species NaTMP·PMDETA
A. Tortajada, E. Hevia
J. Am. Chem. Soc., 2022, 144, 20237
https://pubs.acs.org/doi/abs/10.1021/jacs.2c09778
163. Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX·LiX (X = Cl, Br)
A. Kremsmair, A. S. Sunagatullina, L. J. Bole, P. Mastropierro, S. Graßl, H. R. Wilke, E. Godineau, E. Hevia, P. Knochel
Angew. Chem. Int. Ed. 2022, 61, e202210491
https://onlinelibrary.wiley.com/doi/10.1002/anie.202210491
162. Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent-Induced Dissociation Effects
G. M. Ballmann, T. X. Gentner, A. R. Kennedy, E. Hevia, R. E. Mulvey
Chem. Eur. J. 2022, early view, e202201716
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.202201716
161. Towards Hexagonal Planar Nickel: A Dispersion-Stabilised Tri-Lithium Nickelate
A, M. Borys, L. A. Malaspina, S. Grabowsky, E. Hevia
Angew. Chem. Int. Ed. 2022, 61, e202209797
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202209797
160. Gram-Scale Synthesis, Isolation and Characterisation of Sodium Organometallics: nBuNa and NaTMP
A. Tortajada, D. E. Anderson, E. Hevia
Helv. Chim. Acta, 2022, 105, e202200060
https://onlinelibrary.wiley.com/doi/10.1002/hlca.202200060
159. Enhancing Metalating Efficiency of the Sodium Amide NaTMP in Arene Borylation Applications
L. J. Bole, A. Tortajada, E. Hevia
Angew. Chem. Int. Ed. 2022, 61, e202204262
https://doi.org/10.1002/anie.202204262
158. Alkali Metal Metal(ates) Containing Divalent Earth Abundant Transition Metals
A. Logallo, E. Hevia
Chimia, 2022, 76, 336.
https://doi.org/10.2533/chimia.2022.336
157. Unmasking the constitution and bonding of the proposed lithium nickelate “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand
R. J. Somerville, A. M. Borys, M. Perez-Jimenez, A. Nova, D. Balcells, L. A. Malaspina, S. Grabowsky, E. Carmona, E. Hevia, J. Campos
Chem. Sci. 2022, 13, 5268-5276
https://doi.org/10.1039/D2SC01244H
156. Mechanisms of the Nickel-Catalysed Hydrogenolysis and Cross-Coupling of Aryl Ethers
A. M. Borys, E. Hevia
Synthesis, 2022, 2976-2990
https://www.thieme-connect.com/products/ejournals/abstract/10.1055/a-1806-4513
155. Metallation of Sensitive Fluoroarenes using a Potassium TMP-Zincate Supported by a Silyl(bis)amido Ligand
P. Mastropierro, A. R. Kennedy, E. Hevia
Chem Commun. 2022, 58, 5292
https://doi.org/10.1039/D2CC00979J
154. Activation of polar organometallic reagents with alkali–metal alkoxides
L. J. Bole, E. Hevia
Nature Synthesis, 2022, 1, 195
https://doi.org/10.1038/s44160-022-00040-5
153. Hydrophosphinylation of Styrenes Catalysed by Well-Defined s-Block Bimetallics
A. W. J. Platten, A. M. Borys, E. Hevia
ChemCatChem 2022, 14, e202101853
https://doi.org/10.1002/cctc.202101853
152. Assessing Alkali-Metal Effects in the Structures and Reactivity of Mixed-Ligand Alkyl/Alkoxide Alkali-Metal Magnesiates
N. R. Judge, L. J. Bole, E. Hevia
Chem. Eur. J. 2022, 28, e2021041